Issue 22, 2019

Regression analysis of properties of [Au(IPr)(CHR2)] complexes

Abstract

New [Au(IPr)(CHR2)] complexes have been synthesised through protonolysis reactions of [Au(IPr)(OH)] with moderately acidic substrates, CH2R2. An array of spectroscopic (IR and NMR), structural (X-ray), electronic (DFT) and experimental (reactivity) parameters was collected to quantify the variation in stereoelectronic properties of these new and previously reported [Au(IPr)(CHR2)] complexes. Variation of the R substituents on the carbanion ligands (CHR2) was found to have a crucial impact on parameters characterising the resulting gold complexes. A regression analysis of both experimental and modelled parameters, guided by network analysis techniques, produced linear models that supported trends within the [Au(IPr)(CHR2)] complexes.

Graphical abstract: Regression analysis of properties of [Au(IPr)(CHR2)] complexes

Supplementary files

Article information

Article type
Paper
Submitted
25 Feb 2019
Accepted
26 Apr 2019
First published
07 May 2019

Dalton Trans., 2019,48, 7693-7703

Regression analysis of properties of [Au(IPr)(CHR2)] complexes

R. M. P. Veenboer, L. M. Azofra, D. Gasperini, A. Collado, D. B. Cordes, A. M. Z. Slawin, L. Cavallo and S. P. Nolan, Dalton Trans., 2019, 48, 7693 DOI: 10.1039/C9DT00841A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements