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Issue 10, 2019
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Synthesis and magnetic studies of pentagonal bipyramidal metal complexes of Fe, Co and Ni

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Abstract

Three mononuclear metal complexes [MII(L-N3O2)(MeCN)2][BPh4]2 (M = Fe, 1; Co, 2; Ni, 3) were isolated and structurally characterized. Magnetic studies revealed uniaxial magnetic anisotropy for 1 (D = −17.1 cm−1) and 3 (D = −14.3 cm−1) and easy-plane magnetic anisotropy for 2 (D = +36.9 cm−1). Slow magnetic relaxation was observed for complexes 1 and 2 under an applied magnetic field, both of which are dominated by a Raman process.

Graphical abstract: Synthesis and magnetic studies of pentagonal bipyramidal metal complexes of Fe, Co and Ni

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Publication details

The article was received on 23 Dec 2018, accepted on 13 Feb 2019 and first published on 14 Feb 2019


Article type: Paper
DOI: 10.1039/C8DT05074K
Dalton Trans., 2019,48, 3243-3248

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    Synthesis and magnetic studies of pentagonal bipyramidal metal complexes of Fe, Co and Ni

    Y. Deng, B. Yao, P. Zhan, D. Gan, Y. Zhang and K. R. Dunbar, Dalton Trans., 2019, 48, 3243
    DOI: 10.1039/C8DT05074K

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