Issue 30, 2019
From the journal:

Physical Chemistry Chemical Physics

Rotational spectroscopy of organophosphorous chemical agents: cresyl and phenyl saligenin phosphates†

Rizalina Tama Saragi, ORCID logo a   Marcos Juanes, ORCID logo a   José Luis Abad, ORCID logo b   Alberto Lesarri, ORCID logo *a   Ruth Pinacho ORCID logo c  and  José Emiliano Rubio ORCID logo c  

* Corresponding authors

a Departamento de Química Física y Química Inorgánica – IU CINQUIMA, Facultad de Ciencias, Universidad de Valladolid, 47011 Valladolid, Spain
E-mail: lesarri@qf.uva.es
Web: www.uva.es/lesarri

b Departamento de Química Biológica, Instituto de Química Avanzada de Cataluña (IQAC-CSIC), Consejo Superior de Investigaciones Científicas (CSIC), 08034 Barcelona, Spain

c Departamento de Electrónica, ETSIT, Universidad de Valladolid, 47011 Valladolid, Spain

Abstract

Cresyl and phenyl saligenin phosphates have been probed in a jet expansion by broadband chirp-excitation microwave spectroscopy, revealing the most stable conformations and their structural properties. The rotational parameters offer a high-resolution univocal route for characterization of organophosphorous agents and a testbed for computational models.

Graphical abstract: Rotational spectroscopy of organophosphorous chemical agents: cresyl and phenyl saligenin phosphates

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Article information

DOI
https://doi.org/10.1039/C9CP03093J
Article type
Communication
Submitted
31 May 2019
Accepted
10 Jul 2019
First published
10 Jul 2019

Phys. Chem. Chem. Phys., 2019,21, 16418-16422

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Rotational spectroscopy of organophosphorous chemical agents: cresyl and phenyl saligenin phosphates

R. T. Saragi, M. Juanes, J. L. Abad, A. Lesarri, R. Pinacho and J. E. Rubio, Phys. Chem. Chem. Phys., 2019, 21, 16418 DOI: 10.1039/C9CP03093J

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