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Issue 30, 2019
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Inner-shell X-ray absorption spectra of the cationic series NHy+ (y = 0–3)

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Abstract

Ion yields following X-ray absorption of the cationic series NHy+ (y = 0–3) were measured to identify the characteristic absorption resonances in the energy range of the atomic nitrogen K-edge. Significant changes in the position of the absorption resonances were observed depending on the number of hydrogen atoms bound to the central nitrogen atom. Configuration interaction (CI) calculations were performed to obtain line assignments in the frame of molecular group theory. To validate the calculations, our assignment for the atomic cation N+, measured as a reference, was compared with published theoretical and experimental data.

Graphical abstract: Inner-shell X-ray absorption spectra of the cationic series NHy+ (y = 0–3)

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Publication details

The article was received on 20 May 2019, accepted on 02 Jul 2019 and first published on 22 Jul 2019


Article type: Paper
DOI: 10.1039/C9CP02864A
Phys. Chem. Chem. Phys., 2019,21, 16505-16514
  • Open access: Creative Commons BY license
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    Inner-shell X-ray absorption spectra of the cationic series NHy+ (y = 0–3)

    S. Bari, L. Inhester, K. Schubert, K. Mertens, J. O. Schunck, S. Dörner, S. Deinert, L. Schwob, S. Schippers, A. Müller, S. Klumpp and M. Martins, Phys. Chem. Chem. Phys., 2019, 21, 16505
    DOI: 10.1039/C9CP02864A

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