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Issue 26, 2019
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Polarized fluorescence of a crystal having uniaxially oriented molecules by a carbazole-diyl-bridged macrocage

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Abstract

Polarized fluorescence derived from a molecular structure is characteristic of π-electron systems. Uniaxial molecular alignment can be realized by a crystal of macrocage molecules with a bridged π-electron system. Here, the polarized fluorescence of a single crystal of a carbazole-diyl-bridged macrocage due to the unidirectional orientation of the carbazole moiety inside was observed.

Graphical abstract: Polarized fluorescence of a crystal having uniaxially oriented molecules by a carbazole-diyl-bridged macrocage

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Supplementary files

Article information


Submitted
09 May 2019
Accepted
03 Jun 2019
First published
05 Jun 2019

CrystEngComm, 2019,21, 3910-3914
Article type
Communication

Polarized fluorescence of a crystal having uniaxially oriented molecules by a carbazole-diyl-bridged macrocage

H. Hashimoto, Y. Inagaki, H. Momma, E. Kwon, K. Yamaguchi and W. Setaka, CrystEngComm, 2019, 21, 3910
DOI: 10.1039/C9CE00706G

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