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Issue 26, 2019
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An anionic manganese(II) metal–organic framework for uranyl adsorption

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Abstract

We report herein that an anionic metal–organic framework [Mn5(izdc)3(ox)3] can adsorb uranyl in water with high selectivity (Kd = 2041 mL g−1), large capacity (523 mg g−1) and fast dynamics (KS = 6.68 × 10−3 mg g−1 min−1). Grand canonical Monte Carlo simulation reveals that the coordination effect between the carboxylate O atoms and the equatorial position of the uranyl ion is the key behind this high-performance.

Graphical abstract: An anionic manganese(ii) metal–organic framework for uranyl adsorption

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Publication details

The article was received on 22 Apr 2019, accepted on 05 Jun 2019 and first published on 05 Jun 2019


Article type: Communication
DOI: 10.1039/C9CE00603F
CrystEngComm, 2019,21, 3901-3905

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    An anionic manganese(II) metal–organic framework for uranyl adsorption

    T. Zhang, B. Ling, Y. Hu, T. Han and Y. Zheng, CrystEngComm, 2019, 21, 3901
    DOI: 10.1039/C9CE00603F

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