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Issue 1, 2019
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Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters

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Abstract

The unbalanced MOF-on-MOF growth of MIL-88A on the MIL-88B template, where both MOFs have a similar three-dimensional hexagonal structure but with mismatched cell parameters, results in the formation of an atypical lopsided core–shell of MIL-88B@MIL-88A with an off-centered core. The formation mechanism of the lopsided core–shell of MIL-88B@MIL-88A is verified via monitoring the growth process.

Graphical abstract: Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters

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Article information


Submitted
23 Oct 2018
Accepted
22 Nov 2018
First published
22 Nov 2018

Chem. Commun., 2019,55, 43-46
Article type
Communication

Unbalanced MOF-on-MOF growth for the production of a lopsided core–shell of MIL-88B@MIL-88A with mismatched cell parameters

D. Kim, G. Lee, S. Oh and M. Oh, Chem. Commun., 2019, 55, 43
DOI: 10.1039/C8CC08456D

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