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Issue 91, 2019
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Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin

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Abstract

We report the modification of the 2-ammonio group at halogenated decaborate ions with 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and materials. We demonstrate that these ions present a good binding motif in supramolecular chemistry.

Graphical abstract: Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin

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Submitted
30 Sep 2019
Accepted
21 Oct 2019
First published
21 Oct 2019

Chem. Commun., 2019,55, 13669-13672
Article type
Communication

Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin

S. El Anwar, K. I. Assaf, B. Begaj, M. A. Samsonov, Z. Růžičková, J. Holub, D. Bavol, W. M. Nau, D. Gabel and B. Grűner, Chem. Commun., 2019, 55, 13669
DOI: 10.1039/C9CC07678F

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