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Issue 93, 2019
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Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism)

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Abstract

The hunt for high-performance single-molecule magnets (SMM) revealed that atomic and molecular lanthanide systems combining 4f-shell and valence magnetism (FV-magnetism) may show magnetic bistability up to unexpectedly high temperatures. Here we rationalize the stability of the magnetism in the FV-systems from first principles on the example of LnII(CpiPr5)2 molecules.

Graphical abstract: Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism)

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Submitted
04 Sep 2019
Accepted
28 Oct 2019
First published
28 Oct 2019

Chem. Commun., 2019,55, 13963-13966
Article type
Communication

Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism)

V. Dubrovin, A. A. Popov and S. Avdoshenko, Chem. Commun., 2019, 55, 13963
DOI: 10.1039/C9CC06913E

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