Issue 90, 2019
From the journal:

Chemical Communications

Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces†

Ricarda Pütt,a   Xinkai Qiu,b   Piotr Kozłowski, ORCID logo c   Hans Gildenast,a   Oliver Linnenberg,a   Stefan Zahn, ORCID logo d   Ryan C. Chiechi ORCID logo *b  and  Kirill Yu. Monakhov ORCID logo *d  

* Corresponding authors

a Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany

b Stratingh Institute for Chemistry & Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen 9747 AG, The Netherlands
E-mail: r.c.chiechi@rug.nl

c Faculty of Physics, Adam Mickiewicz University in Poznań, ul. Uniwersytetu Poznańskiego 2, 61-614 Poznań, Poland

d Leibniz Institute of Surface Engineering (IOM), Permoserstraße 15, 04318 Leipzig, Germany
E-mail: kirill.monakhov@iom-leipzig.de

Abstract

The two first representatives of phthalocyaninato (Pc) lanthanide-ligated polyoxovanadate cages {[V12O32(Cl)](LnPc)n}n−5 (n = 1 or 2, Ln = Yb3+) were synthesised and fully characterised. These magnetic complexes form two-dimensional self-assembled monolayers exhibiting electrical conductivity on gold substrate surfaces, as assessed by using an EGaIn tip.

Graphical abstract: Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces

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Article information

DOI
https://doi.org/10.1039/C9CC06852J
Article type
Communication
Submitted
03 Sep 2019
Accepted
14 Oct 2019
First published
14 Oct 2019

Chem. Commun., 2019,55, 13554-13557

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Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces

R. Pütt, X. Qiu, P. Kozłowski, H. Gildenast, O. Linnenberg, S. Zahn, R. C. Chiechi and K. Yu. Monakhov, Chem. Commun., 2019, 55, 13554 DOI: 10.1039/C9CC06852J

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