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Issue 90, 2019
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Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces

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Abstract

The two first representatives of phthalocyaninato (Pc) lanthanide-ligated polyoxovanadate cages {[V12O32(Cl)](LnPc)n}n−5 (n = 1 or 2, Ln = Yb3+) were synthesised and fully characterised. These magnetic complexes form two-dimensional self-assembled monolayers exhibiting electrical conductivity on gold substrate surfaces, as assessed by using an EGaIn tip.

Graphical abstract: Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces

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Article information


Submitted
03 Sep 2019
Accepted
14 Oct 2019
First published
14 Oct 2019

Chem. Commun., 2019,55, 13554-13557
Article type
Communication

Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces

R. Pütt, X. Qiu, P. Kozłowski, H. Gildenast, O. Linnenberg, S. Zahn, R. C. Chiechi and K. Yu. Monakhov, Chem. Commun., 2019, 55, 13554
DOI: 10.1039/C9CC06852J

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