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Issue 93, 2019
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Direct synthesis of dialkylarylvinylsilane derivatives: metathesis of dialkylaryl-iso-propenylsilane and its application to tetracyclic silacycle dye synthesis

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Abstract

The metathesis of dialkylarylvinylsilane, which has not been accomplished to date, is achieved using dialkylaryl-iso-propenylsilane as a substrate. In addition, we discovered that the reason why the metathesis of a ruthenium carbene complex and dialkylarylvinylsilane is difficult is the formation of a carbide complex.

Graphical abstract: Direct synthesis of dialkylarylvinylsilane derivatives: metathesis of dialkylaryl-iso-propenylsilane and its application to tetracyclic silacycle dye synthesis

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Publication details

The article was received on 31 Aug 2019, accepted on 30 Oct 2019 and first published on 30 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06777A
Chem. Commun., 2019,55, 14070-14073

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    Direct synthesis of dialkylarylvinylsilane derivatives: metathesis of dialkylaryl-iso-propenylsilane and its application to tetracyclic silacycle dye synthesis

    S. Yoshioka, T. Takehara, T. Matsuzaki, T. Suzuki, H. Tsujino, T. Uno, Y. Tsutsumi, K. Murai, H. Fujioka and M. Arisawa, Chem. Commun., 2019, 55, 14070
    DOI: 10.1039/C9CC06777A

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