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Issue 71, 2019
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Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

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Abstract

Ni/Cu-cocatalyzed decarbonylative silylation of acyl fluorides with silylboranes has been developed to afford various arylsilanes with high efficiency and good functional-group compatibility via carbon–fluorine bond cleavage and carbon–silicon bond formation. Such transformation can not only extend the functionalization type of acyl fluorides but complement the synthetic route for arylsilanes.

Graphical abstract: Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

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Article information


Submitted
11 Jul 2019
Accepted
05 Aug 2019
First published
05 Aug 2019

Chem. Commun., 2019,55, 10507-10510
Article type
Communication

Nickel/copper-cocatalyzed decarbonylative silylation of acyl fluorides

X. Wang, Z. Wang and Y. Nishihara, Chem. Commun., 2019, 55, 10507
DOI: 10.1039/C9CC05325E

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