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Issue 64, 2019
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Symmetric and non-symmetric bis-metallylene iron complexes, precursors of iron germanide nanoparticles

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Abstract

We report herein the synthesis of symmetric and non-symmetric bis-amidinato-germylene Fe(CO)3 complexes, as well as the preparation of the corresponding disymmetric germylene–stannylene and germylene–silylene complexes by selective displacement of a carbonyl ligand under UV-a light irradiation. The symmetric bis-germylene Fe(CO)3 complex has been applied in the synthesis of iron germanide nanocrystals.

Graphical abstract: Symmetric and non-symmetric bis-metallylene iron complexes, precursors of iron germanide nanoparticles

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Article information


Submitted
02 Jul 2019
Accepted
12 Jul 2019
First published
16 Jul 2019

Chem. Commun., 2019,55, 9539-9542
Article type
Communication

Symmetric and non-symmetric bis-metallylene iron complexes, precursors of iron germanide nanoparticles

A. Sodreau, N. Lentz, M. Frutos, S. Mallet-Ladeira, C. Nayral, F. Delpech and D. Madec, Chem. Commun., 2019, 55, 9539
DOI: 10.1039/C9CC05063A

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