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Issue 63, 2019
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Remote conformational responses to enantiomeric excess in carboxylate-binding dynamic foldamers

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Abstract

A crystallographically characterised zinc(II)-capped foldamer can sense the enantiomeric excess of scalemic carboxylate solutions, including those produced by enantioselective organocatalysis, and can relay this input signal along the foldamer body to a remote glycinamide group, which then provides an NMR spectroscopic output.

Graphical abstract: Remote conformational responses to enantiomeric excess in carboxylate-binding dynamic foldamers

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Article information


Submitted
20 May 2019
Accepted
08 Jul 2019
First published
08 Jul 2019

Chem. Commun., 2019,55, 9331-9334
Article type
Communication

Remote conformational responses to enantiomeric excess in carboxylate-binding dynamic foldamers

N. Eccles, B. A. F. Le Bailly, F. della Sala, I. J. Vitórica-Yrezábal, J. Clayden and S. J. Webb, Chem. Commun., 2019, 55, 9331
DOI: 10.1039/C9CC03895G

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