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Issue 63, 2019
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Topochemical synthesis of phase-pure Mo2AlB2 through staging mechanism

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Abstract

Phase-pure Mo2AlB2 with a single Al layer, a possible precursor for MBenes, was synthesized topochemically by the removal of an Al layer from MoAlB. Ab initio calculations predicted the sequential staging transformation from MoAlB through Mo4Al3B4 (stage II) to Mo2AlB2 (stage I).

Graphical abstract: Topochemical synthesis of phase-pure Mo2AlB2 through staging mechanism

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Publication details

The article was received on 18 May 2019, accepted on 18 Jun 2019 and first published on 18 Jun 2019


Article type: Communication
DOI: 10.1039/C9CC03855H
Chem. Commun., 2019,55, 9295-9298

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    Topochemical synthesis of phase-pure Mo2AlB2 through staging mechanism

    K. Kim, C. Chen, D. Nishio-Hamane, M. Okubo and A. Yamada, Chem. Commun., 2019, 55, 9295
    DOI: 10.1039/C9CC03855H

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