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Issue 56, 2019
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Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy

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Abstract

1H and 13C NMR spectroscopy is used to investigate the organic constituents of metal complexes, MOFs and coordination compounds synthesised under solvothermal and precipitation conditions. The elucidation of the ligands in paramagnetic compounds bearing Cu2+ (d9), Gd3+ (f7), Eu3+ (f6), Fe3+ (d5), ions after treatment with a cationic exchange resin is possible. We prove the efficiency of two post-synthesis linker modifications on diamagnetic IRMOF-3 Zn2+ (d10) with ethyl isocyanate and benzyl bromide.

Graphical abstract: Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy

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Publication details

The article was received on 14 May 2019, accepted on 17 Jun 2019 and first published on 17 Jun 2019


Article type: Communication
DOI: 10.1039/C9CC03721G
Chem. Commun., 2019,55, 8106-8109

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    Ion-exchange resin as a new tool for characterisation of coordination compounds and MOFs by NMR spectroscopy

    A. R. B. D. S. Galaço, K. T. de Oliveira, M. C. Donatoni, R. I. Walton and O. A. Serra, Chem. Commun., 2019, 55, 8106
    DOI: 10.1039/C9CC03721G

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