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Issue 55, 2019
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Macromolecular helicity control of poly(phenyl isocyanate)s with a single stimuli-responsive chiral switch

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Abstract

The introduction of a single chiral substituent with a switchable conformer equilibrium at the poly(phenyl isocyanate) terminus allowed the control of the helical sense of the polymer backbone using various external stimuli. Helical sense enhancement was achieved through a domino effect, where the helical sense was assigned by VCD spectroscopy and DFT calculations.

Graphical abstract: Macromolecular helicity control of poly(phenyl isocyanate)s with a single stimuli-responsive chiral switch

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Article information


Submitted
08 May 2019
Accepted
12 Jun 2019
First published
12 Jun 2019

Chem. Commun., 2019,55, 7906-7909
Article type
Communication

Macromolecular helicity control of poly(phenyl isocyanate)s with a single stimuli-responsive chiral switch

M. Fukuda, R. Rodríguez, Z. Fernández, T. Nishimura, D. Hirose, G. Watanabe, E. Quiñoá, F. Freire and K. Maeda, Chem. Commun., 2019, 55, 7906
DOI: 10.1039/C9CC03555A

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