Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

Caroline M. Zinser; Fady Nahra; Laura Falivene; Marcel Brill; David B. Cordes; Alexandra M. Z. Slawin; Luigi Cavallo; Catherine S. J. Cazin; Steven P. Nolan

doi:10.1039/C9CC03171E

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Synthesis and reactivity of [Au(NHC)(Bpin)] complexes†

Caroline M. Zinser,^a Fady Nahra,

^bc Laura Falivene,^d Marcel Brill,^a David B. Cordes,

^a Alexandra M. Z. Slawin,

^a Luigi Cavallo,

^d Catherine S. J. Cazin

*^b and Steven P. Nolan

*^be

Author affiliations

* Corresponding authors

^a EaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK

^b Department of Chemistry and Center for Sustainable Chemistry, Ghent University, Krijgslaan 281 (S-3), Ghent, Belgium
E-mail: steven.nolan@ugent.be, catherine.cazin@ugent.be

^c VITO (Flemish Institute for Technological Research), Separation and Conversion Technology, Boeretang 200, B-2400 Mol, Belgium

^d Department KAUST Catalysis Centre, KCC, King Abdullah University of Science and Technology, Thuwal-23955-6900, Saudi Arabia

^e Department of Chemistry, College of Science, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi Arabia

Abstract

A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold–boryl complexes exhibit unexpected high stability and reactivity.

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DOI: https://doi.org/10.1039/C9CC03171E
Article type: Communication
Submitted: 24 Apr 2019
Accepted: 14 May 2019
First published: 15 May 2019

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Chem. Commun., 2019,55, 6799-6802

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Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

C. M. Zinser, F. Nahra, L. Falivene, M. Brill, D. B. Cordes, A. M. Z. Slawin, L. Cavallo, C. S. J. Cazin and S. P. Nolan, Chem. Commun., 2019, 55, 6799 DOI: 10.1039/C9CC03171E

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Chemical Communications

Synthesis and reactivity of [Au(NHC)(Bpin)] complexes†

Abstract

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Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

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