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Issue 65, 2019
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Torsional chirality generation based on cyclic oligomers constructed from an odd number of pyrenes

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Abstract

A Ni(0)-mediated coupling reaction of a 1,8-dibromopyrene gave a series of cyclic pyrene oligomers CPn up to nonadecamer. CP5 and CP7 represent a unique class of asymmetric compounds with no stereogenic chiral centers in terms of their global chirality, which are achieved because of an odd number of pyrenes.

Graphical abstract: Torsional chirality generation based on cyclic oligomers constructed from an odd number of pyrenes

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Article information


Submitted
22 Apr 2019
Accepted
10 Jul 2019
First published
10 Jul 2019

Chem. Commun., 2019,55, 9618-9621
Article type
Communication

Torsional chirality generation based on cyclic oligomers constructed from an odd number of pyrenes

R. Kurosaki, M. Suzuki, H. Hayashi, M. Fujiki, N. Aratani and H. Yamada, Chem. Commun., 2019, 55, 9618
DOI: 10.1039/C9CC03123E

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