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Issue 45, 2019
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An exceptionally stable core–shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization–Knoevenagel condensation reaction

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Abstract

A novel strategy has been developed to construct a highly stable core–shell MOF@COF (PCN-222-Co@TpPa-1) bifunctional catalyst through strong π–π stacking interaction. This hybrid material with spatially isolated antagonistic acid–base sites can effectively catalyze the deacetalization–Knoevenagel condensation cascade reaction.

Graphical abstract: An exceptionally stable core–shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization–Knoevenagel condensation reaction

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Article information


Submitted
19 Mar 2019
Accepted
07 May 2019
First published
07 May 2019

Chem. Commun., 2019,55, 6377-6380
Article type
Communication

An exceptionally stable core–shell MOF/COF bifunctional catalyst for a highly efficient cascade deacetalization–Knoevenagel condensation reaction

M. Gao, M. Qi, L. Liu and Z. Han, Chem. Commun., 2019, 55, 6377
DOI: 10.1039/C9CC02174D

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