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Issue 37, 2019
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Redox-responsive phosphonite gold complexes in hydroamination catalysis

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Abstract

Very high activities were observed in the redox-induced hydroamination of alkynes by employing a redox-active gold(I) complex featuring an electron-deficient, terphenyl-substituted phosphonite-based ligand. The hydroamination proceeds roughly two-fold faster with the in situ oxidized catalysts than with their reduced form.

Graphical abstract: Redox-responsive phosphonite gold complexes in hydroamination catalysis

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Article information


Submitted
21 Feb 2019
Accepted
20 Mar 2019
First published
20 Mar 2019

This article is Open Access

Chem. Commun., 2019,55, 5323-5326
Article type
Communication

Redox-responsive phosphonite gold complexes in hydroamination catalysis

E. Deck, H. E. Wagner, J. Paradies and F. Breher, Chem. Commun., 2019, 55, 5323
DOI: 10.1039/C9CC01492F

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