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Issue 29, 2019
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An unprecedented {Ni14SiW9} hybrid polyoxometalate with high photocatalytic hydrogen evolution activity

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Abstract

A unique polyoxometalate complex made up of a tetradecanuclear nickel bisphosphonate cluster capping a {SiW9} unit has been characterized. This stable compound exhibits a high hydrogen evolution reaction photocatalytic activity under visible light irradiation via a reductive quenching mechanism.

Graphical abstract: An unprecedented {Ni14SiW9} hybrid polyoxometalate with high photocatalytic hydrogen evolution activity

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Supplementary files

Article information


Submitted
13 Feb 2019
Accepted
08 Mar 2019
First published
20 Mar 2019

Chem. Commun., 2019,55, 4166-4169
Article type
Communication
Author version available

An unprecedented {Ni14SiW9} hybrid polyoxometalate with high photocatalytic hydrogen evolution activity

G. Paille, A. Boulmier, A. Bensaid, M. Ha-Thi, T. Tran, T. Pino, J. Marrot, E. Rivière, C. H. Hendon, O. Oms, M. Gomez-Mingot, M. Fontecave, C. Mellot-Draznieks, A. Dolbecq and P. Mialane, Chem. Commun., 2019, 55, 4166
DOI: 10.1039/C9CC01269A

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