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Issue 39, 2019
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1H-Detected quadrupolar spin–lattice relaxation measurements under magic-angle spinning solid-state NMR

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Abstract

Proton detection and phase-modulated pulse saturation enable the measurement of spin–lattice relaxation times of “invisible” quadrupolar nuclei with extensively large quadrupolar couplings. For nitrogen-14, efficient cross-polarization is obtained with a long-duration preparation pulse. The experiment paves the way to the characterization of a large variety of materials containing halogens, metals and more.

Graphical abstract: 1H-Detected quadrupolar spin–lattice relaxation measurements under magic-angle spinning solid-state NMR

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Publication details

The article was received on 10 Feb 2019, accepted on 18 Apr 2019 and first published on 18 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC01176E
Chem. Commun., 2019,55, 5643-5646

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    1H-Detected quadrupolar spin–lattice relaxation measurements under magic-angle spinning solid-state NMR

    M. Makrinich and A. Goldbourt, Chem. Commun., 2019, 55, 5643
    DOI: 10.1039/C9CC01176E

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