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Issue 32, 2019
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Substituent changes in the salen ligands of CuIINaI-complexes to induce various structures and catalytic activities towards 2-imidazolines from nitriles and 1,2-diaminopropane

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Abstract

Based on various comparable salen ligands, three synthesized CuIINaI-complexes present efficient catalytic activities for the coupling and cyclization reaction of 1,2-diaminopropane with nitriles towards 2-imidazolines. The catalytic results show that salen ligands with an electron-donating substituent and small steric hindrance improve the catalytic activity.

Graphical abstract: Substituent changes in the salen ligands of CuIINaI-complexes to induce various structures and catalytic activities towards 2-imidazolines from nitriles and 1,2-diaminopropane

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Article information


Submitted
30 Jan 2019
Accepted
19 Mar 2019
First published
20 Mar 2019

Chem. Commun., 2019,55, 4619-4622
Article type
Communication

Substituent changes in the salen ligands of CuIINaI-complexes to induce various structures and catalytic activities towards 2-imidazolines from nitriles and 1,2-diaminopropane

Q. Li, P. He, J. Zhang, J. Zhang, Y. Xin, P. Liu, Y. Wang and J. Li, Chem. Commun., 2019, 55, 4619
DOI: 10.1039/C9CC00879A

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