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Issue 42, 2019
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Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides

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Abstract

A novel reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides has been realized via photoredox/nickel dual catalysis to produce vinyl arene derivatives bearing all-carbon quaternary centers with excellent E-selectivity. A stoichiometric metal reductant could be avoided by employing commercially available N,N,N′,N′-tetramethylethylenediamine (TMEDA) as the terminal reductant.

Graphical abstract: Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides

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Publication details

The article was received on 28 Jan 2019, accepted on 23 Apr 2019 and first published on 24 Apr 2019


Article type: Communication
DOI: 10.1039/C9CC00768G
Chem. Commun., 2019,55, 5918-5921

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    Dual nickel- and photoredox-catalyzed reductive cross-coupling of aryl vinyl halides and unactivated tertiary alkyl bromides

    W. Yu, L. Chen, J. Tao, T. Wang and J. Fu, Chem. Commun., 2019, 55, 5918
    DOI: 10.1039/C9CC00768G

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