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Issue 22, 2019
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Cationic magnesium hydride [MgH]+ stabilized by an NNNN-type macrocycle

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Abstract

A magnesium hydride cation [(L)MgH]+ supported by a macrocyclic ligand (L = Me4TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH2Mg{N(SiMe3)2}2] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.

Graphical abstract: Cationic magnesium hydride [MgH]+ stabilized by an NNNN-type macrocycle

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Publication details

The article was received on 19 Jan 2019, accepted on 13 Feb 2019 and first published on 14 Feb 2019


Article type: Communication
DOI: 10.1039/C9CC00490D
Chem. Commun., 2019,55, 3199-3202

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    Cationic magnesium hydride [MgH]+ stabilized by an NNNN-type macrocycle

    L. E. Lemmerz, D. Mukherjee, T. P. Spaniol, A. Wong, G. Ménard, L. Maron and J. Okuda, Chem. Commun., 2019, 55, 3199
    DOI: 10.1039/C9CC00490D

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