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Issue 32, 2019
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The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

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Abstract

A post-synthesis thermal treatment of metastable phases in the high-pressure stabilised perovskite BiFe1−yScyO3 system results in the irreversible formation of polymorphs which represent novel polar and antipolar structures with interesting magnetic properties. Such annealing-stimulated polymorphism is believed to be a general phenomenon which can be found in other systems.

Graphical abstract: The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

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Supplementary files

Article information


Submitted
18 Jan 2019
Accepted
25 Mar 2019
First published
26 Mar 2019

Chem. Commun., 2019,55, 4683-4686
Article type
Communication

The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

D. D. Khalyavin, A. N. Salak, E. L. Fertman, O. V. Kotlyar, E. Eardley, N. M. Olekhnovich, A. V. Pushkarev, Y. V. Radyush, A. V. Fedorchenko, V. A. Desnenko, P. Manuel, L. Ding, E. Čižmár and A. Feher, Chem. Commun., 2019, 55, 4683
DOI: 10.1039/C9CC00472F

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