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Issue 32, 2019
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Gold(ii) in redox-switchable gold(i) catalysis

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Abstract

Gold(II) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the saturated gold(I) complex is inactive. Redox-switching between gold(II) and gold(I) turns catalytic turnover on and off.

Graphical abstract: Gold(ii) in redox-switchable gold(i) catalysis

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Article information


Submitted
11 Jan 2019
Accepted
01 Mar 2019
First published
01 Mar 2019

Chem. Commun., 2019,55, 4615-4618
Article type
Communication

Gold(II) in redox-switchable gold(I) catalysis

P. Veit, C. Volkert, C. Förster, V. Ksenofontov, S. Schlicher, M. Bauer and K. Heinze, Chem. Commun., 2019, 55, 4615
DOI: 10.1039/C9CC00283A

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