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Issue 15, 2019
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Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices

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Abstract

A multi-configurable catalyst, for which the degree of enantioinduction in successive reactions is varied between 6% ee and 52% ee, is achieved by supporting copper centres at the periphery of supramolecular helices. Precise characterization of the co-assemblies corroborates the relation between helix length and catalyst selectivity.

Graphical abstract: Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices

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Supplementary files

Article information


Submitted
11 Dec 2018
Accepted
18 Jan 2019
First published
18 Jan 2019

Chem. Commun., 2019,55, 2162-2165
Article type
Communication

Modulation of catalyst enantioselectivity through reversible assembly of supramolecular helices

Y. Li, X. Caumes, M. Raynal and L. Bouteiller, Chem. Commun., 2019, 55, 2162
DOI: 10.1039/C8CC09819K

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