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Issue 17, 2019
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A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands†

Akira Nagai,a   Takashi Nakamura ORCID logo a  and  Tatsuya Nabeshima ORCID logo *a  
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* Corresponding authors

a Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
E-mail: nabesima@chem.tsukuba.ac.jp

Abstract

A macrocyclic hexanuclear palladium complex, which accumulates coordination sites on metals inside the cavity, was synthesized. The macrocycle was found to take a uniquely-twisted C2-symmetric conformation when six molecules of a bulky pyridine derivative coordinated to the palladium.

Graphical abstract: A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

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Article information

https://doi.org/10.1039/C8CC09643K
Submitted
04 Dec 2018
Accepted
08 Jan 2019
First published
09 Jan 2019
Chem. Commun., 2019,55, 2421-2424
Article type
Communication
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A twisted macrocyclic hexanuclear palladium complex with internal bulky coordinating ligands

A. Nagai, T. Nakamura and T. Nabeshima, Chem. Commun., 2019, 55, 2421
DOI: 10.1039/C8CC09643K

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