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Issue 17, 2019
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Structural evolution in a melt-quenched zeolitic imidazolate framework glass during heat-treatment

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Abstract

A pronounced enthalpy release occurs around 1.38Tg in the prototypical metal–organic framework glass formed from ZIF-4 [Zn(C3H3N2)2], but there is no sign for any crystallization (i.e., long-range ordering) taking place. The enthalpy release peak is attributed to pore collapse and structural densification.

Graphical abstract: Structural evolution in a melt-quenched zeolitic imidazolate framework glass during heat-treatment

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Publication details

The article was received on 03 Dec 2018, accepted on 04 Feb 2019 and first published on 04 Feb 2019


Article type: Communication
DOI: 10.1039/C8CC09574D
Chem. Commun., 2019,55, 2521-2524

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    Structural evolution in a melt-quenched zeolitic imidazolate framework glass during heat-treatment

    J. Zhang, L. Longley, H. Liu, C. W. Ashling, P. A. Chater, K. A. Beyer, K. W. Chapman, H. Tao, D. A. Keen, T. D. Bennett and Y. Yue, Chem. Commun., 2019, 55, 2521
    DOI: 10.1039/C8CC09574D

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