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Issue 13, 2019
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Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

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Abstract

Electrochemically driven interfacial halogen bonding between redox-active SAMs and halide anions was quantitatively studied for the first time. The halogen bond donor properties were switched on by electrochemically controlling the oxidation state of the adsorbates. Experimental data and simulation show high binding enhancement towards halide anions compared to homogeneous systems.

Graphical abstract: Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

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Article information


Submitted
06 Nov 2018
Accepted
21 Jan 2019
First published
22 Jan 2019

Chem. Commun., 2019,55, 1983-1986
Article type
Communication

Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

H. Hijazi, A. Vacher, S. Groni, D. Lorcy, E. Levillain, C. Fave and B. Schöllhorn, Chem. Commun., 2019, 55, 1983
DOI: 10.1039/C8CC08856J

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