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Issue 13, 2019
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Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

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Abstract

Electrochemically driven interfacial halogen bonding between redox-active SAMs and halide anions was quantitatively studied for the first time. The halogen bond donor properties were switched on by electrochemically controlling the oxidation state of the adsorbates. Experimental data and simulation show high binding enhancement towards halide anions compared to homogeneous systems.

Graphical abstract: Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

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Publication details

The article was received on 06 Nov 2018, accepted on 21 Jan 2019 and first published on 22 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC08856J
Chem. Commun., 2019,55, 1983-1986

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    Electrochemically driven interfacial halogen bonding on self-assembled monolayers for anion detection

    H. Hijazi, A. Vacher, S. Groni, D. Lorcy, E. Levillain, C. Fave and B. Schöllhorn, Chem. Commun., 2019, 55, 1983
    DOI: 10.1039/C8CC08856J

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