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Issue 2, 2019
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A spin crossover porous hybrid architecture for potential sensing applications

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Abstract

Spin crossover cations have been successfully synthesized in the pores of a mesoporous robust Metal–Organic Framework (MOF) MIL-100(Al) through sequential introduction of Fe(III) cations and a sal2trien ligand. The MIL-100(Al)@Fe(sal2trien) hybrid material retains its crystallinity and partial porosity compared to the parent MOF. The spin state of the Fe(sal2trien)+ cations can be modulated at room temperature through sorption of guest molecules, paving the way to the design of a new generation of sensors based on MOF@spin crossover complex solids.

Graphical abstract: A spin crossover porous hybrid architecture for potential sensing applications

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Supplementary files

Article information


Submitted
19 Sep 2018
Accepted
27 Nov 2018
First published
28 Nov 2018

Chem. Commun., 2019,55, 194-197
Article type
Communication

A spin crossover porous hybrid architecture for potential sensing applications

A. Tissot, X. Kesse, S. Giannopoulou, I. Stenger, L. Binet, E. Rivière and C. Serre, Chem. Commun., 2019, 55, 194
DOI: 10.1039/C8CC07573E

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