Issue 5, 2019

The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(iv) compounds

Abstract

Perovskite-derived hybrid platinum iodides with the general formula A2PtIVI6 (A = formamidinium FA and guanidinium GUA) accommodate excess I2 to yield hydrogen-bond-stabilized compounds where the I2 forms catenates with I anions on the PtI6 octahedra.

Graphical abstract: The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(iv) compounds

  • This article is part of the themed collection: Perovskites

Supplementary files

Article information

Article type
Communication
Submitted
18 Sep 2018
Accepted
19 Nov 2018
First published
27 Nov 2018

Chem. Commun., 2019,55, 588-591

Author version available

The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(IV) compounds

H. A. Evans, J. L. Andrews, D. H. Fabini, M. B. Preefer, G. Wu, A. K. Cheetham, F. Wudl and R. Seshadri, Chem. Commun., 2019, 55, 588 DOI: 10.1039/C8CC07536K

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