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Insight into chirality on molecular stacking for tunable ultralong organic phosphorescence

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Abstract

A new levorotatory compound ((S)-9,9′-(6-(1-phenylethoxy)-1,3,5-triazine-2,4-diyl)bis(9H-carbazole)) and its corresponding racemic compound show different intermolecular interactions to restrain nonradiative transition, resulting in an enhanced ultralong organic phosphorescence lifetime from 229.0 ms to 419.8 ms. This work will provide a new insight into the chirality of organic molecules to adjust the ultralong phosphorescence.

Graphical abstract: Insight into chirality on molecular stacking for tunable ultralong organic phosphorescence

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Publication details

The article was received on 05 Jul 2018, accepted on 02 Sep 2018 and first published on 03 Sep 2018


Article type: Communication
DOI: 10.1039/C8TC03297A
Citation: J. Mater. Chem. C, 2018, Advance Article
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    Insight into chirality on molecular stacking for tunable ultralong organic phosphorescence

    C. Ma, H. Ma, K. Ling, R. Zheng, M. Gu, L. Song, Z. An, H. Shi and W. Huang, J. Mater. Chem. C, 2018, Advance Article , DOI: 10.1039/C8TC03297A

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