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Fluorescence Modulation by Fast Photochromism of [2.2]Paracyclophane-Bridged Imidazole Dimer Possessing a Perylene Bisimide Moiety

Abstract

The development of single-molecule imaging and super-resolution microscopic tequniques has promoted the study of fluorescence switchable molecules that have been important for the in-depth understanding of activities of organelles and geometries of materials in nano- and microscales. The utilization of photochromic compounds as the photo-switching trigger is one of the efficient strategies to reversibly control the fluorescent “ON” and “OFF” states. In this study, we demonstrated the red-color fluorescence switching of a perylene bisimide (PBI) derivative by using the fast photochromic [2.2]paracyclophane-bridged imidazole dimer. The transient colored biradical species as the fluorescence quencher is generated upon UV light irradiation. Because the biradical species has broad absorption bands in the whole visible light and the near-infrared regions (500–900 nm), the fluorescence of PBI could be efficiently quenched by Förster resonance energy transfer (FRET). The fluorescence intensity was switched by the fast photochromic cycles within a few tens of milliseconds. The potential capability of the transient biradical species to switch the fluorescence in the visible and NIR regions will open up new possibilities in multicolor fluorescence imaging.

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Publication details

The article was received on 04 Jun 2018, accepted on 05 Aug 2018 and first published on 07 Aug 2018


Article type: Paper
DOI: 10.1039/C8TC02713G
Citation: J. Mater. Chem. C, 2018, Accepted Manuscript
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    Fluorescence Modulation by Fast Photochromism of [2.2]Paracyclophane-Bridged Imidazole Dimer Possessing a Perylene Bisimide Moiety

    K. Mutoh, M. SLIWA, E. Fron, J. Hofkens and J. Abe, J. Mater. Chem. C, 2018, Accepted Manuscript , DOI: 10.1039/C8TC02713G

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