Issue 31, 2018

Enhanced thermoelectric performance of Sn-doped Cu3SbS4


Cu3SbS4 is an earth-abundant and low-cost alternative thermoelectric material for medium temperature applications. Tin doping into Cu3SbS4 yields materials with high thermoelectric performance. The electronic structure of Sn-doped Cu3SbS4 was studied using both hybrid density functional theory (DFT) and the quasi-particle self-consistent GW (QSGW) approach. A synthesis method involving mechanical alloying (MA) and spark plasma sintering (SPS) was employed to produce dense and single phase Cu3SbS4 samples with very fine grain size. Previously unreported nano-scale twins on {112} planes were observed by transmission electron microscopy (TEM). All of the samples showed very low lattice thermal conductivity, which is attributed to their microstructures. Sn was found to substitute Sb successfully in Cu3SbS4 and work effectively as an acceptor dopant, leading to an enhanced power factor. A maximum zT value of 0.72 at 623 K was achieved in Cu3Sb1−xSnxS4 (x = 0.05), which is comparable to the Se analogue Cu3SbSe4.

Graphical abstract: Enhanced thermoelectric performance of Sn-doped Cu3SbS4

Supplementary files

Article information

Article type
22 May 2018
23 Jun 2018
First published
01 Aug 2018
This article is Open Access
Creative Commons BY license

J. Mater. Chem. C, 2018,6, 8546-8552

Enhanced thermoelectric performance of Sn-doped Cu3SbS4

K. Chen, C. Di Paola, B. Du, R. Zhang, S. Laricchia, N. Bonini, C. Weber, I. Abrahams, H. Yan and M. Reece, J. Mater. Chem. C, 2018, 6, 8546 DOI: 10.1039/C8TC02481B

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