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Issue 47, 2018
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A donor–acceptor semiconducting polymer with a random configuration for efficient, green-solvent-processable flexible solar cells

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Abstract

Morphologies and optoelectronic/mechanical properties of semiconducting polymers are significantly affected by their configurations. In this study, thiophene units are introduced into the backbone of a semiconducting polymer in either a regular (PffBT-T4) or a random (PffBT-RT4) manner to determine whether the resulting semiconducting polymers are suitable for developing efficient polymer solar cells. The energy levels of both polymers are highly similar because they share the same ratio of subunits in their backbones; however, PffBT-RT4 has lower crystallinity than PffBT-T4 due to its random configuration. Microstructural analyses indicate that PffBT-RT4 exhibits a shorter π–π stacking distance than PffBT-T4. Since short π–π stacking distance benefits interchain charge transport, PffBT-RT4 shows higher space-charge-limited current mobility, and PffBT-RT4 solar cells exhibit higher power conversion efficiency (PCE; 8.84%) than their PffBT-T4 counterparts (7.25%). In addition, PffBT-RT4 solar cells with active layers, prepared using a green solvent without any additive, show an encouraging PCE of 7.23%. Moreover, flexible solar cells based on PffBT-RT4 are much more stable during bending cycles than PffBT-T4 flexible solar cells. Therefore, this study demonstrates that the random configuration approach is a promising design strategy to realize semiconducting polymers for efficient, green-solvent-processable flexible polymer solar cells.

Graphical abstract: A donor–acceptor semiconducting polymer with a random configuration for efficient, green-solvent-processable flexible solar cells

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Supplementary files

Article information


Submitted
17 Oct 2018
Accepted
19 Nov 2018
First published
19 Nov 2018

J. Mater. Chem. A, 2018,6, 24580-24587
Article type
Paper

A donor–acceptor semiconducting polymer with a random configuration for efficient, green-solvent-processable flexible solar cells

S. Y. Son, J. W. Kim, J. Lee, G. Kim, J. Hong, J. Y. Kim and T. Park, J. Mater. Chem. A, 2018, 6, 24580
DOI: 10.1039/C8TA10015B

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