Jump to main content
Jump to site search

Issue 45, 2018
Previous Article Next Article

La-doped BaSnO3 electron transport layer for perovskite solar cells

Author affiliations

Abstract

Due to the photoinstability and large hysteresis of the TiO2 electron transport layer (ETL) in perovskite solar cells (PSCs), the search for novel electron transport materials has emerged. Herein, using first principles calculations, we unveiled the key factor for the ideal band alignment between La-doped BaSnO3 (LBSO) and methyl ammonium (MA) lead iodide perovskite (MAPbI3). The (PbI2-, MAI-terminated)CH3NH3PbI3/(SnO2-, BaO-terminated)LaxBa(1−x)SnO3 interface formed a stable “all-perovskite” heterostructure with large binding energy. The selective band alignment of the conduction band was easily manipulated by La-doping on the Ba site due to the band gap renormalization (or shrinkage) caused by doped electrons and La3+ dopant. In addition, the MAI-terminated MAPbI3/LBSO interface exhibited proton transfer (BaO-terminated) and strong hydrogen bonding (SnO2-terminated) between MA and oxygen anion. LBSO presenting high mobility, photostability, and structural stability would help develop the next generation ETL materials for PSCs.

Graphical abstract: La-doped BaSnO3 electron transport layer for perovskite solar cells

Back to tab navigation

Supplementary files

Publication details

The article was received on 10 Sep 2018, accepted on 23 Oct 2018 and first published on 23 Oct 2018


Article type: Paper
DOI: 10.1039/C8TA08764D
Citation: J. Mater. Chem. A, 2018,6, 23071-23077
  •   Request permissions

    La-doped BaSnO3 electron transport layer for perovskite solar cells

    C. W. Myung, G. Lee and K. S. Kim, J. Mater. Chem. A, 2018, 6, 23071
    DOI: 10.1039/C8TA08764D

Search articles by author

Spotlight

Advertisements