Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.

Issue 45, 2018
Previous Article Next Article

Chemically soft solid electrolyte interphase forming additives for lithium-ion batteries

Author affiliations


The solid electrolyte interphase (SEI) layer is a key element of lithium-ion batteries (LIBs) enabling stable operation and significantly affecting the cycling performance including life-length. Here we present the concept of chemically soft SEI-forming additives, created by introducing aromatic ring based derivatives of already well-known SEI-formers to render them chemically soft, resulting in 1,3,2-benzodioxathiole 2,2-dioxide (DTDPh), 3H-1,2-benzoxathiole 2,2-dioxide (PSPh), and 1,4,2-benzodioxathiine 2,2-dioxide (PSOPh). A computational DFT based comparison predicts promise with respect to both early and controlled reduction processes. These predictions are verified by basic electrochemical studies targeting appropriate additive reduction potentials i.e. prior to any electrolyte solvent or salt decomposition. In addition, the decomposition paths of the SEI-formers are projected and the end products compared with spectroscopic data for the SEI-layers formed in LIB cells. The SEI-layers formed finally show very good properties in terms of improved capacity retention, improved coulombic efficiency, and reduced resistance for the graphite/electrolyte/LFP full cells made, especially observed for PSOPh. That is due to the preferred C–O bond breaking mechanism, observed also for DTDPh, and supported by the S–C bond breaking mechanism, together resulting in well conductive and good adhesion properties of the SEI-layers. This is expedited by higher softness, eventuating in a formation process stabilizing some of the radicals and/or lowering the kinetic barriers. These positive effects are confirmed both when applying a commercial style electrolyte and for a new generation electrolyte based on the LiTDI salt, where suppression of the TDI anion reduction is truly crucial.

Graphical abstract: Chemically soft solid electrolyte interphase forming additives for lithium-ion batteries

Back to tab navigation

Supplementary files

Publication details

The article was received on 15 Aug 2018, accepted on 12 Oct 2018 and first published on 15 Oct 2018

Article type: Paper
DOI: 10.1039/C8TA07936F
Citation: J. Mater. Chem. A, 2018,6, 22609-22618

  •   Request permissions

    Chemically soft solid electrolyte interphase forming additives for lithium-ion batteries

    P. Jankowski, M. Poterała, N. Lindahl, W. Wieczorek and P. Johansson, J. Mater. Chem. A, 2018, 6, 22609
    DOI: 10.1039/C8TA07936F

Search articles by author