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Issue 44, 2018
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Tolerance factors of hybrid organic–inorganic perovskites: recent improvements and current state of research

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Abstract

In 2014 we applied Goldschmidt's concept of ionic tolerance factors to the large family of hybrid organic–inorganic perovskites. Initially seen as a guiding concept for the discovery of new hybrid organic–inorganic perovskites, the tolerance factor concept has also proven to be a valuable tool for understanding and manipulating the phase stability and properties of existing phases. Since our initial report, there have been many research examples in which tolerance factors were used to understand the existence and stability of certain hybrid organic–inorganic perovskites, while the concept itself has been continuously improved. Here we give an update on the current state of the concept, reviewing the different improvements that have been made over the past few years and drawing on topical examples in which tolerance factors have played a major role.

Graphical abstract: Tolerance factors of hybrid organic–inorganic perovskites: recent improvements and current state of research

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Publication details

The article was received on 17 Jun 2018, accepted on 07 Sep 2018 and first published on 07 Sep 2018


Article type: Review Article
DOI: 10.1039/C8TA05794J
Citation: J. Mater. Chem. A, 2018,6, 21785-21793
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    Tolerance factors of hybrid organic–inorganic perovskites: recent improvements and current state of research

    S. Burger, M. G. Ehrenreich and G. Kieslich, J. Mater. Chem. A, 2018, 6, 21785
    DOI: 10.1039/C8TA05794J

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