Issue 36, 2018
From the journal:

Journal of Materials Chemistry A

Illuminating the nature and behavior of the active center: the key for photocatalytic H2 production in Co@NH2-MIL-125(Ti)†

Ana Iglesias-Juez, ORCID logo *a   Sonia Castellanos, ORCID logo *b   Manuel Monte,c   Giovanni Agostini, ORCID logo ‡c   Dmitrii Osadchii,d   Maxim A. Nasalevich,d   Jara G. Santaclara,d   Alma I. Olivos Suarez, ORCID logo d   Sergey L. Veber,e   Matvey V. Fedin ORCID logo e  and  Jorge Gascón ORCID logo df  

* Corresponding authors

a Instituto de Catálisis y Petroleoquímica, CSIC, 28049 Madrid, Spain
E-mail: ana.iglesias@icp.csic.es

b Advanced Research Center for Nanolithography, 1090 BA Amsterdam, The Netherlands
E-mail: s.castellanos@arcnl.nl

c European Synchrotron Radiation Facility, 38000 Grenoble, France

d Catalysis Engineering, Applied Sciences, Delft University of Technology, Julianalaan 136, Delft, The Netherlands

e International Tomography Center SB RAS, Novosibirsk State University, Novosibirsk 630090, Russia

f King Abdullah University of Science and Technology, KAUST Catalysis Center, Advanced Catalytic Materials, Thuwal 23955, Saudi Arabia

Abstract

Advanced atomically resolved characterization methods unveil the mechanism of a promising photocatalytic Co@MOF(Ti) system for H2 production. The combination of X-ray absorption spectroscopy (XAS) and electron paramagnetic resonance (EPR) experiments allows for the characterization of atomic and electronic rearrangements in the photoinduced species. This information provides the basis for the optimization of photocatalyst design.

Graphical abstract: Illuminating the nature and behavior of the active center: the key for photocatalytic H2 production in Co@NH2-MIL-125(Ti)

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Article information

DOI
https://doi.org/10.1039/C8TA05735D
Article type
Communication
Submitted
15 Jun 2018
Accepted
16 Aug 2018
First published
22 Aug 2018

J. Mater. Chem. A, 2018,6, 17318-17322

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Illuminating the nature and behavior of the active center: the key for photocatalytic H2 production in Co@NH2-MIL-125(Ti)

A. Iglesias-Juez, S. Castellanos, M. Monte, G. Agostini, D. Osadchii, M. A. Nasalevich, J. G. Santaclara, A. I. Olivos Suarez, S. L. Veber, M. V. Fedin and J. Gascón, J. Mater. Chem. A, 2018, 6, 17318 DOI: 10.1039/C8TA05735D

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