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Highly Flexible, Foldable and Stretchable Ni-Co Layered Double Hydroxide/Polyaniline/Bacterial Cellulose Electrodes for High-performance All-Solid-State Supercapacitors

Abstract

A novel flexible nickel-cobalt layered double hydroxide/polyaniline/bacterial cellulose (NiCo-LDH/PANI/BC) electrode with both excellent electrochemical and mechanical performance is obtained through successively coating PANI and NiCo-LDH on BC. In addition to make the 3D open network (BC) conductive, the PANI layer also functions as a “nanoglue” to uniformly and robustly immobilize nanostructured NiCo-LDH onto the highly enlarged surface of PANI/BC nanofibers owing to its rough surface and hydrophilicity. Benefitting from the hierarchical structure with 3D conductive network, unobstructed channels, numerous electroactive sites and induced synergistic effect, the NiCo-LDH/PANI/BC electrode shows excellent electrochemical performance in aqueous electrolyte, exhibiting a high specific capacitance of 1690 F g-1 (761 C g-1) at 1 A g-1, enhanced rate capability (778 F g-1 or 350 C g-1 at 15 A g-1) and outstanding cycling stability (83.2% capacitance retention after 5000 cycles). Besides, the NiCo-LDH/PANI/BC also shows excellent foldability, high tensile strength (90.8±4.9 MPa), high breaking elongation (7.2±0.7%) and outstanding electrochemical stability during bending and stretching. Moreover, a flexible all-solid-state supercapacitor is assembled with NiCo-LDH/PANI/BC as the positive electrode and N-doped carbonized BC/carbon cloth as the negative electrode, delivering a high energy density of 47.3 Wh kg−1 at the power density of 828.9 W kg−1, and superior cycling stability (91.4% capacitance retention after 3000 cycles). Therefore, this work provides a new path for high-performance flexible energy storage devices and offers a new vision for uniformly and robustly assembling nanohybrids.

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Publication details

The article was received on 14 Jun 2018, accepted on 01 Aug 2018 and first published on 01 Aug 2018


Article type: Paper
DOI: 10.1039/C8TA05673K
Citation: J. Mater. Chem. A, 2018, Accepted Manuscript
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    Highly Flexible, Foldable and Stretchable Ni-Co Layered Double Hydroxide/Polyaniline/Bacterial Cellulose Electrodes for High-performance All-Solid-State Supercapacitors

    H. Wu, Y. Zhang, W. Yuan, Y. Zhao, S. Luo, X. Yuan, L. Zheng and L. Cheng, J. Mater. Chem. A, 2018, Accepted Manuscript , DOI: 10.1039/C8TA05673K

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