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Issue 27, 2018
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Flexible metal-templated fabrication of mesoporous onion-like carbon and Fe2O3@N-doped carbon foam for electrochemical energy storage

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Abstract

Nanostructured carbon materials have served as potent electrode materials and crucial components for energy storage; however, multi-function integration of the synthesis route is hugely challenging. Consequently, we report herein a facile and general methodology for the synthesis of multifunctional materials, specifically mesoporous onion-like carbon (OLC) and core–shell Fe2O3@N-doped carbon hybrids, derived from water soluble gelatin and ferric nitrate precursors, which could function as high-performance electrodes for supercapacitors (SCs) and Li-ion batteries (LIBs). Owing to the strong chelation effect between the abundant functional groups of gelatin chains and metal ions, in situ-formed uniform confined nanoparticles (NPs) in a three-dimensional (3D) carbon framework could exert the triple roles of templates, graphitizing catalysts, and active materials via controllable annealing. Mesoporous OLC-3 with hollow core size of 5–8 nm, high specific surface area of 418 m2 g−1, thin shells of 3–5 graphitic layers, and rich oxygen content (18.62%) exhibited a remarkable specific capacitance (251.2 F g−1 at 0.5 A g−1), surpassing most OLC state-of-the-art SC electrodes. Besides, the as-obtained core-shelled Fe2O3@N-doped carbon annealed at 500 °C composed of a gelatin-derived carbon-coating layer (ca. 4 nm) and uniform Fe2O3 core (ca. 30 nm) greatly enhanced the rate capability (achieving an average reversible capacity of 735.9 mA h g−1 at 0.1 A g−1 and 480.6 mA h g−1 at a large current density of 2 A g−1) and demonstrated an excellent cycling life (372 mA h g−1 after 500 cycles at 1 A g−1, or 0.39 mA h g−1 decay per cycle) for Li storage. This method is quite flexible and could be also extended to the synthesis of other metal-based functional materials.

Graphical abstract: Flexible metal-templated fabrication of mesoporous onion-like carbon and Fe2O3@N-doped carbon foam for electrochemical energy storage

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Publication details

The article was received on 15 Mar 2018, accepted on 26 Apr 2018 and first published on 26 Apr 2018


Article type: Paper
DOI: 10.1039/C8TA02417K
J. Mater. Chem. A, 2018,6, 13012-13020

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    Flexible metal-templated fabrication of mesoporous onion-like carbon and Fe2O3@N-doped carbon foam for electrochemical energy storage

    J. Li, N. Wang, J. Deng, W. Qian and W. Chu, J. Mater. Chem. A, 2018, 6, 13012
    DOI: 10.1039/C8TA02417K

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