Development of highly effective CaO@Al2O3 with hierarchical architecture CO2 sorbents via a scalable limited-space chemical vapor deposition technique

Abstract

High-temperature sorption of CO₂via calcium looping is a promising technology for the implementation of carbon capture and storage (CCS). However, the major drawback of this technology is the rapid deactivation of CaO sorbents due to sintering. Here, a facile and cost-effective limited-space metal organic chemical vapor deposition approach is proposed to develop CaO-based sorbents exhibiting a very high and cyclically stable CO₂ uptake. The TEM results show that Al₂O₃ nanoparticles (4–8 nm) are uniformly coated onto CaO crystalline grains, thus effectively inhibiting the sintering of sorbents. After 20 severe cycles, the synthetic sorbent, stabilized by 10 mol% Al₂O₃, exceeded the CO₂ uptake of the benchmark CaO by more than 300%. Furthermore, the influence of Ca-based precursors on the synthetic sorbent's cyclic CO₂ uptake was established. The result shows that the sorbents synthesized from different Ca-based precursors all demonstrate high cycling stability, which means that low-cost and high-performance sorbents can be synthesized through selecting a low-cost Ca precursor, such as CaCO₃.