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Issue 39, 2018
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Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)

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Abstract

We present an unexpected self-assembly of a glycoluril clip–poly(ε-caprolactone) conjugate in chloroform. The conjugate forms homodimer aggregates due to supramolecular interactions between glycoluril moieties, which was confirmed with MALDI-TOF-ms and 1H NMR. TEM revealed the formation of multilayered nanosized prism-shaped objects resembling tree bark in nature.

Graphical abstract: Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)

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Publication details

The article was received on 30 Aug 2018, accepted on 11 Sep 2018 and first published on 13 Sep 2018


Article type: Communication
DOI: 10.1039/C8SM01777H
Citation: Soft Matter, 2018,14, 7945-7949
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    Homodimerization driven self-assembly of glycoluril molecular clips with covalently immobilized poly(ε-caprolactone)

    M. Gosecka, M. Urbaniak, M. Mikina, M. Gosecki and A. Rozanski, Soft Matter, 2018, 14, 7945
    DOI: 10.1039/C8SM01777H

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