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Compound Droplets Derived from a Cholesteric Suspension of Cellulose Nanocrystals


This study reports microfluidic generation of Janus droplets that consist of a liquid crystal component (a cholesteric aqueous suspension of cellulose nanocrystals, Ch-CNC) and a mineral oil (MO) component. The composition of the droplets was controlled by varying the relative flow rates of MO and Ch-CNC suspension. The shape of the Ch-CNC component of the droplets was changed from a truncated sphere to a hemisphere to a crescent moon. For these three Ch-CNC phase shapes, the Ch packing of the CNC pseusolayers was preserved, however the Ch pitch reduced, which was ascribed to the change in CNC orientation at the Ch-CNC/MO interface from perpendicular to parallel. The shape of the compound droplets was tuned from a dumbbell to a sphere by reducing interfacial tension between the Ch-CNC suspension and MO phases. Photopolymerization of the monomer mixture introduced in the Ch-CNC phase of the droplets and the removal of the sacrificial MO phase enabled the generation of Ch microgels. The results of this work can be used for exploring new applications of Janus colloids and the fabrication of programmable active soft matter.

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Publication details

The article was received on 21 Aug 2018, accepted on 06 Nov 2018 and first published on 08 Nov 2018

Article type: Paper
DOI: 10.1039/C8SM01716F
Citation: Soft Matter, 2018, Accepted Manuscript
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    Compound Droplets Derived from a Cholesteric Suspension of Cellulose Nanocrystals

    T. SUZUKI, Y. Li, A. Gevorkian and E. Kumacheva, Soft Matter, 2018, Accepted Manuscript , DOI: 10.1039/C8SM01716F

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