Cs3VO(O2)2CO3: an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response†
A novel nonlinear optical (NLO) carbonatoperoxovanadate, Cs3VO(O2)2CO3, with an exceptionally high thermostability was successfully synthesized by introducing highly polarizable Cs+ cations and inorganic polydentate carbonate anions into asymmetric peroxovanadates. The structure of Cs3VO(O2)2CO3 is composed of distorted [VO(O2)2CO3]3− units and charge balancing Cs+ cations. The title compound exhibits the largest NLO intensity ever found in the current carbonate NLO materials, i.e., 23.0 times that of KH2PO4 (KDP). The remarkably strong second-harmonic generation (SHG) response originates from the synergistic effect of the exceedingly polarizable Cs+ cations, distortive polyhedra of the V5+ cation, delocalized π orbitals in CO3 groups, and distorted localized π orbitals in O2 groups. First-principles calculations indicated that introducing the polarizable cations into peroxovanadates not only induces the enhancement of the SHG response but also improves the thermal stability of the framework.
- This article is part of the themed collections: Most popular 2018-2019 materials chemistry articles, 2018 ChemSci Pick of the Week Collection and 2018 Chemical Science HOT Article Collection