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Silyl enol etherification by a Tf2NH/amine co-catalytic system for minimizing hazardous waste generation

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Abstract

A practical silyl enol etherification of ketones with allylsilanes catalyzed by a Tf2NH–amine co-catalyst under mild conditions has been developed. The reaction generated only volatile isobutene gas as waste. Moreover, a multi-gram synthesis using a microfluidic system and a domino silyl enol etherification–(2 + 2) cycloaddition reaction were demonstrated.

Graphical abstract: Silyl enol etherification by a Tf2NH/amine co-catalytic system for minimizing hazardous waste generation

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Publication details

The article was received on 07 Mar 2018, accepted on 11 Jul 2018 and first published on 11 Jul 2018


Article type: Communication
DOI: 10.1039/C8RE00039E
Citation: React. Chem. Eng., 2018, Advance Article
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    Silyl enol etherification by a Tf2NH/amine co-catalytic system for minimizing hazardous waste generation

    K. Kurahashi, Y. Yamaoka, Y. Takemoto and K. Takasu, React. Chem. Eng., 2018, Advance Article , DOI: 10.1039/C8RE00039E

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