Incorporation of potassium halides in the mechanosynthesis of inorganic perovskites: feasibility and limitations of ion-replacement and trap passivation

Abstract

Potassium halides (KX; X = I, Br, or Cl) were incorporated as partial replacements of CsBr in the mechanosynthesis of CsPbBr₃. This led to partial substitution of both monovalent ions forming mixed Cs_1−xK_xPbBr_3−yX_y perovskites. Longer photoluminescence lifetimes were also observed, possibly linked to the formation of a non-perovskite KPb₂X₅ passivating layer.